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After killing the Sphynx's (destoyers) in AQ20, a obsidian ore chunk falls to the ground and is minable. You need 305 mining to mine the 1 Small obsidian shard that comes out of it.
Just get the +5 mining to a pair of crappy gloves and you can switch gloves when you need to mine the ore.
Used in Blacksmithing:
- Small Obsidian shard: http://www.thottbot.net/?i=53165
- Large Obsidian shard: http://www.thottbot.net/?i=53172